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The electrochemical insertion of lithium in the spinel-type manganite with the formula ZnNiyMn2–yO4 has been studied. The galvanostatic discharge curves show that the best performance is obtained for y = 0.25, where a tetragonal to cubic structural transformation occurs. The thermodynamics and kinetics of the process of insertion of the lithium into the tetragonal spinel LixZnNi0.25Mn1.75O4...
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