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PbYb0.5Nb0.5O3 (PYN)‐based ceramics, featured by their ultra‐high phase‐switching field and low sintering temperature (950 °C), are of great potential in exploiting dielectric ceramics with high energy storage density and low preparation cost. However, due to insufficient breakdown strength (BDS), their complete polarization‐electric field (P‐E) loops are difficult to be obtained. Here, to fully reveal...
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