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An original methodology based on microchip electrophoresis in a continuous frontal analysis mode (FACMCE) was employed to provide new insights into the interaction between an aptamer and its target (lysozyme), i.e., the influence of various experimental conditions on possible conformation change of the aptamer. The parameters evaluated were: background electrolyte (BGE) nature and ionic strength,...
Microemulsion electrokinetic chromatography (MEEKC) has been widely used as an indirect tool to measure octanol–water partition coefficients (logPow) of various kinds of compounds. In this paper, we present for the first time a mathematical model of the precision of logPow (ΔlogPow) as a function of the deviation of migration time (Δtm) in MEEKC, and more importantly evaluated the accuracy of...
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