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Herein, we report the employment of the MoMo quintuple bonded amidinate complex to stabilize Group 10 metal fragments {(Et3P)2M} (M=Pd, Pt) and give rise to the isolation of the unprecedented δ complexes. X‐ray analysis unambiguously revealed short contacts between Pd or Pt and two Mo atoms and a slight elongation of the MoMo quintuple bond in these two compounds. Computational studies show donation...
Seit der Entdeckung des Zeise‐Salzes im Jahr 1827 …︁ …︁ wurden zahllose Übergangsmetall‐Hauptgruppenelement‐π‐Komplexe und ‐σ‐Komplexe synthetisiert und charakterisiert. Die Bindungsverhältnisse werden am besten anhand des Dewar‐Chatt‐Modells wiedergegeben. In der Zuschrift auf S. 9234 ff. zeigen Y.‐C. Tsai et al. nun, dass Metall‐Metall‐Bindungen, etwa eine Mo‐Mo‐Fünffachbindung, als Liganden wirken...
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