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The present review is focused on the mechanistic discussion of the polymerization of multiallyl monomers including diallyl dicarboxylates, multiallyl hydroxycarboxylates, TAIC, allyl oxalates, multiallylammonium chlorides, allyl vinyl monomers, and others, based on experimental results obtained mainly in our laboratory. In particular, the inherent properties of these polymers and the mechanism for...
Neopentyl glycol dimethacrylate was polymerized in bulk in the presence of lauryl mercaptan as a chain transfer agent, the primary chain length being reduced to a comparable order in allyl polymerization, and the gelation behavior was compared with diallyl terephthalate (DAT) polymerization as a typical example of multiallyl polymerizations. No Trommsdorff effect was observed, even beyond the gel...
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