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Two pure mixed alkali-transition metal borates, Li6Zn3B4O12(s) and Na3ZnB5O10(s) have been synthesized and characterized by XRD, FT-IR, and chemical analysis. For Li6Zn3B4O12, the molar enthalpy of solution of Li6Zn3B4O12 in the mixture solvent of {2.00 mL of 1 mol·L−1 HCl + H3BO3)(aq)} was measured. The molar enthalpies of solution of ZnO(s) in 1 mol·L−1 HCl(aq), and LiBO2(s) in the mixture solvent...
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