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This chapter reviews recent advances in the synthesis of polyelectrolytes. New results are presented for linear polymers with stiff and flexible backbones and with star-shaped and randomly branched structures. Block Block and graft copolymers graft copolymers containing both charged ionic and hydrophobic monomer units are also discussed. Homo- and block copolymers of carbobetaines complete the variation...
Polyelectrolyte block copolymers form micelles and vesicles in aqueous solutions. Micelle formation and micellar structure depends on various parameters like block lengths, salt concentration, pH, and solvent quality. The synthesis and properties of more complicated block and micellar architectures such as triblock- and graft copolymers, Janus micelles, and core-shell cylinder brushes are reviewed...
Polyelectrolyte block copolymers form micelles and vesicles in aqueous solutions. Micelle formation and micellar structure depends on various parameters like block lengths, salt concentration, pH, and solvent quality. The synthesis and properties of more complicated block and micellar architectures such as triblock- and graft copolymers, Janus micelles, and core-shell cylinder brushes are reviewed...
This chapter reviews recent advances in the synthesis of polyelectrolytes. New results are presented for linear polymers with stiff and flexible backbones and with star-shaped and randomly branched structures. Block Block and graft copolymers graft copolymers containing both charged ionic and hydrophobic monomer units are also discussed. Homo- and block copolymers of carbobetaines complete the variation...
Tailoring the size and surface chemistry of nanoparticles allows one to control their position in a block copolymer, but this is usually limited to one‐dimensional distribution across domains. Here, the hierarchical assembly of poly(ethylene oxide)‐stabilized gold nanoparticles (Au‐PEO) into hexagonally packed clusters inside mesostructured ultrathin films of polystyrene‐block‐poly(methyl methacrylate)...
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