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The intermetallic compound (IC) formation between Pd and Ce via reductive metal-support interaction (RMSI) has been studied using two different Pd/CeO2 materials: A thin film of Pd particles embedded in fluorite-type CeO2, grown on vacuum-cleaved NaCl(001) facets and CeO2 powder impregnated with small Pd particles. The reduction of CeO2 and formation of different Pd-Ce intermetallic compounds has...
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