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A mononuclear titanium single crystal C36H40O8Si3Ti was synthesized and designed as a molecular precursor to produce silica supported single site Ti decorated Au catalysts of high activity and selectivity. Single site Ti–O species were successfully deposited onto Au nanoparticles supported on SiO2 by simple grafting procedures. X-ray absorption spectroscopy and diffuse reflectance ultraviolet spectroscopies...
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