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A novel porphyrin derivative 5,10,15,20-tetra-4′-(tert-butylthio)phenylporphyrin (abbreviated as TSPP) and its Zn (II) complex (Zn-TSPP) have been synthesized and characterized, which possess aggregation-induced emission enhancement (AIEE) properties. The bulky groups increase the intermolecular steric effects which impede the π–π stacking interactions inducing J-aggregates of the two compounds in...
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