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Molecular sequential doping using conjugated polymers is a promising approach to modulate or improve electrical conductivity without sacrificing the morphology of a pristine polymer film. In article number 2005129, Hyungtak Seo, Jong H. Kim, Bong‐Gi Kim, and co‐workers develop a cascade doping strategy that realizes excellent electrical conductivity through a separated doping process using two different...
Doping capability is primitively governed by the energy level offset between the highest occupied molecular orbital (HOMO) of conjugated polymers (CPs) and the lowest unoccupied molecular orbital (LUMO) of dopants. A poor doping efficiency is obtained when doping directly using NOBF4 forming a large energy offset with the CP, while the devised doping strategy is found to significantly improve the...
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