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A new polyamine macrobicyclic compound was synthesised through a [1+1] “tripod–tripod coupling” strategy and using a Schiff base condensation reaction, followed by sodium borohydride reduction. The resulting compound is a heteroditopic cage (btpN7) in which one of the head units is appropriate for the coordination of copper(II), whereas the other head is available for additional hydrogen‐bonding and...
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