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A new concept on the direct synthesis of middle iso-paraffins through the modified supercritical Fischer–Tropsch (FT) reaction was proposed and experimentally demonstrated with the combination of Co/SiO 2 and palladium-supported β zeolite (Pd/β) catalysts both in one-stage and two-stage fixed-bed reaction systems. Depending on the reaction conditions, the selectivity of C 4+ iso-paraffins...
This paper focuses on the synthesis of iso-paraffin-rich hydrocarbons by Fischer-Tropsch synthesis (FTS) over Co/SiO 2 catalyst. The basic concept was to secondarily isomerize and/or hydrocrack the primary FTS hydrocarbon products.A physical mixture of a small amount of added H-ZSM-5 in the Co/SiO 2 catalyst enhanced the formation of C 4 -C 10 iso-paraffins while...
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