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The infiltration of cytotoxic T lymphocytes (CTLs) in tumors is critically challenged by the intricate intratumor physical barriers, which is emerging as an important issue of anticancer immunotherapy. Herein, a reduction‐sensitive nitric oxide donor conjugate of furoxans–oxaliplatin is synthesized and a stroma‐cell‐accessible bioinspired lipoprotein system (S‐LFO) is designed, aiming to facilitate...