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Reactions of the trinuclear iron cluster [Fe 3 Cp 2 (CO) 3 (μ-CO)(μ 3 -CO)(μ 3 -CF 3 C 2 CF 3 )] (1) with the bis(phosphino) ligands dppm and dppe give different results: dppe yields mainly the hexanuclear compound (2) in which two tri-iron cluster units are linked by the diphosphine, although a trinuclear derivative (3) with a chelating...
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