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The influence of Gd addition on the microstructure of Zr56Co28Al16 metallic glasses was investigated for the exchange of Zr by up to 20 at.% Gd. Due to the large positive enthalpy of mixing between Zr and Gd, liquid–liquid phase separation occurs during rapid quenching of the melt. For a low concentration of Gd (x=2 at.%), a homogeneous amorphous structure is obtained for the as-quenched state. Early...
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