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Due to their large surface areas, tunable functionality, and diversiform building blocks, metal–organic frameworks (MOFs) have arisen great attention in the last few decades. Nevertheless, most of MOFs show poor water stability, which seriously hinders their further applications. In this study, through the immobilization of polyoxometalate in a water unstable cage-based MOF material {[(Cu4Cl)(CPT)...
To further explore the research of the coordination possibilities of lanthanide ions with m-/p-hydroxybenzoic acid isomers in the presence of chelating N-donor ligand 1,10-phenanthroline (phen), six lanthanide supramolecular frameworks based on 3- and 4-hydroxybenzoic acids, namely [Dy(m-L)(m-HL)(phen)]·H2O (1) (m-H2L=3-hydroxybenzoic acid), [Ln(m-HL)3(phen)] (Ln=Gd for 2 and Tb for 3), [Ln(p-HL)3...
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