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Two new indium arsenic(III) oxide halides, In2(As2O5)Cl2 (1) and In4(As2O5)(As3O7)Br3 (2), have been prepared by solid‐state reaction. Both of the compounds feature layered structures, in which indium–oxide halide octahedral rings or indium–oxo chains are bridged by indium–oxide halide octahedral dimers or indium–oxo unicapped trigonal prisms, and the interlinkage between the rings or chains is also...
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