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Solvent effects on the reaction equilibrium of the 1‐dodecene hydroformylation in a decane/N,N‐dimethylformamide solvent system is investigated. The reaction was performed at different decane/N,N‐dimethylformamide ratios and at temperatures between 368 K and 388 K. The equilibrium concentrations of all reactants and products were determined experimentally. The enthalpy and Gibbs energy of this reaction...
In this work, Δ R g + values for the enzymatic G6P isomerization were determined as a function of the G6P equilibrium molality between 25°C and 37°C. The reaction mixtures were buffered at pH=8.5. In contrast to standard literature work, Δ R g + values were determined from activity-based equilibrium constants instead of molality-based apparent values. This yielded a...
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