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The interaction of hydrogen peroxide, ascorbate and microperoxidase-11 (MP11), a ferriheme undecapeptide derived from cytochrome c, has been investigated using spectrophotometry, oxymetry, electron paramagnetic resonance (EPR), and mass spectroscopy techniques. It is shown that in 50m M phosphate pH 7.0–7.4 in the absence of other reactants H2O2induces a concentration-dependent decrease in absorption...
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