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The copper(II) and zinc(II) complexes of N,N-bis(benzimidazole-2-ylmethyl)amine (L) have been prepared and the crystal structure of [ZnLCl 2 ]. MeOH determined. The complex is five-coordinate with a distorted square pyramidal geometry on zinc. Two pyridine nitrogen donors from the imidazole groups, the secondary amino group and one chloride act as in-plane donors with the axial site occupied...
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