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The effect of reaction conditions (such as the amount of sulfuric acid, reaction temperature and feeding style of reactants) on the product distribution in the green oxidation of cyclohexene to adipic acid was investigated. This reaction, with 30% hydrogen peroxide as oxidant in the presence of a homogeneous peroxy tungstate catalyst, is of great industrial interest for not using of organic solvent...
Tungsten peroxo complexes have been widely used in olefin epoxidation, alcohol oxidation, Baeyer–Villiger oxidation and other oxidation reactions, however, there is still not a unanimous viewpoint for the active structure of mononuclear tungsten peroxo complex by now. In this paper, the catalysis of mononuclear tungsten peroxo complexes 0–5 with or without acidic ligands for the green oxidation of...
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