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The paper reports the peculiar structural behavior of RNiIn deuterides. The RNiIn compounds with (R = La, Ce, Pr, Nd) are known as exhibiting unusually short H–H (D–D) interatomic distances of about 1.6 Å (two hydrogen atoms within the R 3 Ni 2 polyhedron). In our paper, the synthesis procedure and structural data for RNiIn deuterides with R = La, Nd, Gd, Tb, Dy, Ho, Er are presented...
REIr 2 Si 2 (RE = La, Ce, Pr and Nd) were found to be polymorphic compounds which can crystallize in two different tetragonal types of crystallographic structures (β-phase: CaBe 2 Ge 2 -type; α-phase: ThCr 2 Si 2 -type). Here we study the structural phase transitions (α- to β- and β- to α-) using thermal expansion, differential thermal analysis and neutron...
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