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Two 2D metal–organic coordination polymers were synthesized through solvothermal reactions. The formation of 2D supramolecular networks was driven by intermolecular π–π stacking interactions between 2,2′-bipyridyl units of 1D coordination polymer chains. These 2D networks showed large cavities and windows for encapsulation of guest molecules. The networks showed weak antiferromagnetic exchange interactions...
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