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N,N,N',N'-tetramethyldianilines are well known donor modules tailored to π,π-interaction driven self-assembly processes. When N,N,N',N'-tetramethyl-1,4-phenylenediamine (1a) and bis[4-(N,N-dimethylaminophenyl)]methane (1c) interact with 1,4-diiodotetrafluorobenzene (2), the halogen bonding organises the perfluorocarbon and hydrocarbon modules into the one dimensional linear networks 3a,c overcoming...
Heteroaromatic N-oxides are shown to work as effective electron donors towards perfluorocarbon iodides. This non-covalent interaction is strong enough to drive the self-assembly of perfluorocarbon and hydrocarbon modules into discrete aggregates or one dimensional infinite networks and to give rise to the shortest O...I intermolecular distance reported to now in the crystallographic literature. The...
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