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Polycrystalline sample of sodium cobalt triphosphate NaCo(PO3)3 was obtained by solid-state reaction and characterized by X-ray powder diffraction. The title compound is isostructural to NaZn(PO3)3 and its structure was refined by the Rietveld refinement in the cubic system, space group Pa3̅, with a=14.2484(4)Å. The obtained structural model is supported by bond valence sum (BVS) and charge distribution...
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