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TiO 2 photocatalysis of adamantane in oxygen equilibrated MeCN yields 1- and 2-adamantanol and adamantanone with limited degradation and preference for functionalization at the 1 position, particularly in the presence of silver salts. Oxidation in CH 2 Cl 2 is less selective. The oxidation of cyclohexane and cyclododecane is slower. In N 2 -flushed solutions with Ag...
The photocatalytic oxidation of dodecane and some of its derivatives (C 12 H 26 , 1; C 10 H 21 CH CH 2 , 2; C 12 H 25 SH, 3; C 12 H 25 OH, 4; C 12 H 25 NH 2 , 5; C 11 H 23 CHO, 6) has been studied in air-equilibrated aqueous TiO...
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