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Es wird ein adaptives katalytisches System vorgestellt, das die Kontrolle über das Nitroaren‐Hydrierungsnetzwerk zur Herstellung einer breiten Palette von Anilin‐ und Hydroxylaminderivaten ermöglicht. Dieses System profitiert von einem delikaten Zusammenspiel zwischen einem Rhodium(III)‐Zentrum und einem Lewis‐sauren Boran, das in die sekundäre Koordinationssphäre des Metalls eingeführt wird. Die...
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