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In order to determine an equilibrium structure of phenylpentamethyldisilane in the S 0 and S 1 states, high-resolution laser-induced fluorescence spectra were measured. An analysis of rotational envelopes of the 0 00 and 6b 01 bands was carried out. As a result, the most stable form was found to be a configuration in which the disilanyl group lies in a plane...
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