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The ruthenium-catalyzed highly linear selective allylic amination of monosubstituted allylic acetates with secondary amines was developed. The regioselectivity was controlled by the Ru 3 (CO) 12 /2-DPPBA catalyst, and a linear-type aminated product was obtained as a single regioisomer.
The palladium-catalyzed regioselective allylic amination of α-trifluoromethylated allyl acetate occurred using Pd(OAc) 2 /DPPE and [Pd(π-allyl)(cod)]BF 4 /DPPF. The selective formation of the γ-product was attained by Pd(OAc) 2 /DPPE, while the α-product was obtained using [Pd(π-allyl)(cod)]BF 4 /DPPF.
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