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A lumped kinetic model of methyl butanoate pyrolysis and oxidation is presented and discussed in this work. The hierarchical approach first required the development and validation of sub-mechanisms of small esters such as methyl formate, methyl acrylate and methyl crotonate. A broad-ranging validation of the whole kinetic scheme of methyl butanoate oxidation was then carried out through comparisons...
The aim of this work is to present and discuss a detailed kinetic model that describes the devolatilization process of solid fuels under pyrolysis conditions. The major reason for this interest in better understanding pyrolysis and combustion of coal, biomasses and solid fuels lies in the increasing concern for the environmental impact of large scale combustion processes. The common chemical and structural...
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