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Highly active Ni2P catalyst supported on core-shell structured Al2O3@TiO2 for hydrodeoxygenation (HDO) of benzofuran (BF) was prepared and the effect of water on the performance for BF HDO over as-prepared catalyst was studied. The hydrophobic TiO2 shell can enhance the catalytic activity, water resistance and HDO stability of the Ni2P/Al2O3 catalyst. The Ni2P/A@T exhibited the highest HDO activity...
A novel and simple surface modification approach for preparing a highly active nickel phosphide hydrodeoxygenation (HDO) catalyst is proposed, in which the original nickel phosphide catalyst is modified with oxygen at 373K under a flow of air for 1h instead of being passivated with an O2/N2 mixture. In this way, no pre-treatment of the catalyst prior to reaction is needed. The effect of surface modification...
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