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The conductivity of poly(3,4-ethylenedioxythiophene)–poly(styrenesulfonic) acid (PEDOT–PSS) thin-films was increased by up to 900 times with the addition of linear-diols. Three series of linear-diols were investigated. It is proposed that three mechanisms contribute to improved conductivity; conformational changes in the polymer from coil to expanded, spatial separation of PEDOT–PSS grains and charge...
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