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Phenanthrene hydrogenation is a key reaction for improving the quality of gasoline and diesel. Herein, we conduct detailed thermodynamic and kinetic analyses for phenanthrene hydrogenation on a Ni‐Mo/HY catalyst. We establish a comprehensive reaction network for phenanthrene hydrogenation, and calculate equilibrium constant, rate constant, adsorption constant, activation energy barrier, and reaction...
Numerous hydride‐abstracting agents generate the same cationic intermediate, but substrate features such as intermediate cation stability, oxidation potential, and steric environment can influence reaction rates in an oxidant‐dependent manner. This manuscript provides experimental data to illustrate the role that structural features play in the kinetics of hydride abstraction reactions with commonly...