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In contrast to the much larger grain size of the binder phase in traditional WC–Co cemented carbide, we have achieved a significantly reduced grain size of the γ′-Ni3Al strengthened composite binder phase in WC–Co–Ni–Al cemented carbide. Based on thermodynamic calculations, decisive experiments and microstructure characterizations, the formation mechanism for grain size of binder phase in WC–Co–Ni–Al...
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