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The rare‐earth local environments of Nd:Al2O3‐P2O5‐K2O glass with different P/Al ratios are analyzed using electron paramagnetic resonance (EPR). The echo‐detected field sweep (EDFS) line‐shape change hints at a modification of the local environment around Nd3+ ion by various P/Al ratios. The coordination sphere structure of Nd3+ ion is determined by three and four pulse electron spin echo envelope...
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