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Two groups of polyacrylate latexes with higher (21 ~ 35 °C) or lower (−33 ~ −43 °C) glass transition temperatures (Tg) were prepared by adjusting the monomer ratio of butyl acrylate (BA) and styrene (St), and the effect of acrylic acid (AA) on water‐whitening resistance of these latex films was investigated. It was found that the water‐whitening resistance of the two groups of latex films was different...