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This paper reports the formation of styrene monomer, dimer and trimer in the primary volatiles during fast pyrolysis of polystyrene in a wire-mesh reactor where secondary reactions of primary pyrolysis volatiles are minimized. Styrene monomer is the most abundant product in the primary volatiles from polystyrene pyrolysis, with a selectivity of 48–69wt% depending on pyrolysis temperature, while dimer...
The study aims to understand the fundamental mechanism of the pyrolysis of polyvinylchloride (PVC) by investigating the chars produced in a wire-mesh reactor, where the interactions of evolving volatiles and pyrolysing PVC particles as well as the secondary reactions of the volatiles are minimized. The initiation of PVC pyrolysis can start at a temperature as low as 200°C on the surface of PVC particles...
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