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In a recent experimental study it has been shown, that fluorine-containing bismuth vanadate (F:BiVO4) reveals enhanced photoelectrochemical activity compared to pristine BiVO4. This work is a combined experimental and theoretical analysis of structural and electronic properties of F:BiVO4. A theoretical analysis of three different possible defect models for F:BiVO4 was carried out. The structures...
CN-mayenite (Ca 12 Al 14 O 32 (CN) 2 ) is a promising candidate for high-temperature CN − conductivity in a solid due to its special structural features. It was prepared by a solid–gas reaction. The transport processes were investigated by means of in situ high-temperature neutron diffraction, impedance spectroscopy and additional Hebb–Wagner measurements. Diffusion...
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