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The gas phase isomerization of styrene oxide (STO) into phenylacetaldehyde (PhAD) in good yield and selectivity has been achieved using a steel tube reactor as catalyst in an efficient and environmentally friendly process. Under semi-optimized conditions (240 °C, N2 flow) a steel tube reactor filled with steel balls gave a selectivity of PhAD of 99% at 98% STO conversion. Use of an equivalent glass...
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