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Two novel tetradentate bis-cyclometalated platinum (IV) complexes of TPA-2q-PtCl2 and 3TPA-2q-PtCl2 with CˆN*NˆC cyclometalated ligands and two coordinated chlorine atoms were synthesized and characterized. The crystal structure of TPA-2q-PtCl2 shows a trans-form irregular octahedral geometry by measurement of single-crystal X-ray diffraction, where two CˆN coordination moieties are twisted and two...
Two novel tetradentate platinum (II) salophen complexes A and B, respectively substituted by dual donor-accepter frameworks of phenazine-triphenylamine in the heads and waists of salophen, were synthesized and characterized. By changing the substituted positions of dual phenazine-triphenylamine units, different optophysical, electrochemical and electroluminescent properties were remarkably observed...
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