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Bilayer semiconductors have attracted much attention due to their stacking‐order‐dependent properties. However, as both 3R‐ and 2H‐stacking are energetically stable at high temperatures, most of the high‐temperature grown bilayer materials have random 3R‐ or 2H‐stacking orders, leading to non‐uniformity in optical and electrical properties. Here, a chemical vapor deposition method is developed to...
2D material‐based heterostructures are constructed by stacking or spicing individual 2D layers to create an interface between them, which have exotic properties. Here, a new strategy for the in situ growth of large numbers of 2D heterostructures on the centimeter‐scale substrate is developed. In the method, large numbers of 2D MoS2, MoO2, or their heterostructures of MoO2/MoS2 are controllably grown...
In recent years, 2D layered semiconductors have received much attention for their potential in next‐generation electronics and optoelectronics. Wide‐bandgap 2D semiconductors are especially important in the blue and ultraviolet wavelength region, although there are very few 2D materials in this region. Here, monolayer β‐type zirconium nitride chloride (β‐ZrNCl) is isolated for the first time, which...
Monolayer transition metal dichalcogenides are 2D materials with many potential applications. Chemical vapor deposition (CVD) is a promising method to synthesize these materials. However, CVD‐grown materials generally have poorer quality than mechanically exfoliated ones and contain more defects due to the difficulties in controlling precursors' distribution and concentration during growth where solid...
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