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Anion solvation in electrolytes can largely change the electrochemical performance of the electrolytes, yet has been rarely investigated. Herein, three anions of bis(trifluoromethanesulfonyl)imide (TFSI), bis(fluorosulfonyl)imide (FSI), and derived asymmetric (fluorosulfonyl)(trifluoro‐methanesulfonyl)imide (FTFSI) are systematically examined in a weakly Li+ cation solvating solvent of bis(3‐fluoropropyl)ether...
Anion Solvation
In article number 2306462, Jijian Xu, Anh T. Ngo, Chunsheng Wang, and co‐workers reveal anion solvation (anion‐solvent interaction) as a new direction to rational design the electrolyte for lithium metal batteries and beyond to achieve high performance. This study completes the understanding of the complex interplay among the electrolyte components (solvents, Li+, anions), which can...
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