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We present the results of novel type additives to improve the cathode cycleability performance. Benzene derivatives (biphenyl and o-terphenyl) and heterocyclic compounds (furan, thiophene, N-methylpyrrole and 3,4-ethylenedioxythiophene), which have lower oxidation potentials than those of electrolyte solvents are picked up. We use MO calculations in the selection of additives and prove that the calculated...
Several olefinic compounds such as vinyl acetate, divinyl adipate and allyl methyl carbonate were studied as additives for propylene carbonate (PC)-based electrolytes in lithium-ion battery, which kind of electrolytes always exfoliate graphitic carbon and decompose drastically to liberate organic gas. Three kinds of graphitic carbons commonly used in lithium-ion batteries, namely, natural graphite,...
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