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Sauerstoffreduktion. H. Su, H. Sato et al. zeigen in der Zuschrift auf dass B‐Dotierung die Dissoziationsbarriere von O2 an Pd‐Nanopartikeln für die Sauerstoffreduktionsreaktion (ORR) senkt.
A highly active alternative to Pt electrocatalysts for the oxygen reduction reaction (ORR), which is the cathode‐electrode reaction of fuel cells, is sought for higher fuel‐cell performance. Our theoretical modelling reveals that B‐doped Pd (Pd‐B) weakens the absorption of ORR intermediates with nearly optimal binding energy by lowering the barrier associated with O2 dissociation, suggesting Pd‐B...
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