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Solid polymer electrolytes based on plastic crystals are promising for solid‐state sodium metal (Na0) batteries, yet their practicality has been hindered by the notorious Na0‐electrolyte interface instability issue, the underlying cause of which remains poorly understood. Here, by leveraging a model plasticized polymer electrolyte based on conventional succinonitrile plastic crystals, we uncover its...
Solid polymer electrolytes based on plastic crystals are promising for solid‐state sodium metal (Na0) batteries, yet their practicality has been hindered by the notorious Na0‐electrolyte interface instability issue, the underlying cause of which remains poorly understood. Here, by leveraging a model plasticized polymer electrolyte based on conventional succinonitrile plastic crystals, we uncover its...
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