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Au nanoparticles (NPs) from 2.1 to 6.2nm and Pt NPs in 2–3nm were supported on the amide functional silica (SiO 2 -N). The effect of particle size on the catalytic activity was investigated by the 1,3-butadiene hydrogenation reaction. Based on thermal conductivity detector (TCD) signal, the reaction is size-dependent. The highest turnover frequency (TOF) occurs at a particle size of ~3nm,...
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