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Pushed over the edge: Proton‐transfer coupled O2 reduction catalysed by cobalt phthalocyanine ([CoPc]) was studied at the water/1,2‐dichloroethane (DCE) interface (see figure). This system represents a new model of molecular electrocatalysis with the proton transfer controlled by the Galvani potential difference and the electron transfer by the molecular properties of the catalyst and electron donor.
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