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Single‐atom transition metals present extraordinary activity but are hard to be synthesized and stabilized. In their Research Article (e202312292), Jiafeng Yu, Anna Zimina, Jian Sun et al. created SiO2‐stabilized single‐site Zr species by the flame spray pyrolysis (FSP) method, unlocking a dual‐channel pathway for CO2 hydrogenation to methanol reaction. A “seesaw effect” limitation between the competitive...
Das bisher unbekannte Disilavinyliden‐Molekül (H2SiSi), das hier vor seinem differenziellen Reaktionsquerschnitt abgebildet ist, wird in der Gasphasenreaktion von atomarem Silicium mit Silan (SiH4) gebildet und tritt im Gleichgewicht mit den monoverbrückten Si(H)SiH‐ und diverbrückten Si(H2)Si‐Isomeren auf. Wie R. I. Kaiser, A. H. H. Chang, J. F. Stanton et al. in ihrer Zuschrift auf S. 1284 zeigen,...
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