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We report three DTBDT-based small molecules with various end groups and the effects of end-group tuning on their photovoltaic properties. We designed and synthesized DTBDT-Rho, DTBDT-EC, and DTBDT-CN, which have 3-ethylrhodanine, dicyanovinyl, and ethyl cyanoacetate, respectively, as end groups. DTBDT-EC and DTBDT-CN have much deeper LUMO and HOMO energy levels than DTBDT-Rho due to the stronger electron...
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